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Extract from the Register of European Patents

EP About this file: EP2821409

EP2821409 - Metal alkylidene complexes comprising an unsymmetrical unsaturated NHC ligand [Right-click to bookmark this link]
StatusThe application is deemed to be withdrawn
Status updated on  27.11.2015
Database last updated on 23.04.2024
Most recent event   Tooltip27.11.2015Application deemed to be withdrawnpublished on 30.12.2015  [2015/53]
Applicant(s)For all designated states
Centre National de la Recherche Scientifique (C.N.R.S.)
3 rue Michel-Ange
75794 Paris Cedex 16 / FR
For all designated states
Ecole Nationale Supérieure de Chimie de Rennes
Campus de Beaulieu
Avenue du Général Leclerc, CS 50837
35708 Rennes Cedex 7 / FR
[N/P]
Former [2015/02]For all designated states
Centre National de la Recherche Scientifique (CNRS)
3, rue Michel-Ange
75794 Paris Cedex 16 / FR
For all designated states
Ecole Nationale Supérieure de Chimie de Rennes
Campus de Beaulieu
Avenue du Général Leclerc, CS 50837
35708 Rennes Cedex 7 / FR
Inventor(s)01 / Mauduit, Marc
36 rue Nicolas Copernic
35500 Vitré / FR
02 / Basle, Olivier
1 rue de Nemours
35000 Rennes / FR
03 / Queval, Pierre
Les Appelais
35520 La Chapelle des Fougeretz / FR
04 / Jahier, Claire
6 rue Millig Ar Skanv di Glenmor
bat C, Appt 32
35235 Thorigné-Fouillard / FR
05 / Artur, Isabelle
31 bd Léon Bourgeois
35500 Rennes / FR
 [2015/02]
Representative(s)Palacci, Jeremie
Cabinet Netter
36, avenue Hoche
75008 Paris / FR
[2015/02]
Application number, filing date13175362.605.07.2013
[2015/02]
Filing languageEN
Procedural languageEN
PublicationType: A1 Application with search report 
No.:EP2821409
Date:07.01.2015
Language:EN
[2015/02]
Search report(s)(Supplementary) European search report - dispatched on:EP18.03.2014
ClassificationIPC:C07F15/00, B01J31/22, C07F1/08, C07F1/10, C07F1/12
[2015/02]
CPC:
C07F1/08 (EP); C07F1/10 (EP); C07F1/12 (EP);
C07F15/0033 (EP); C07F15/006 (EP); C07F15/008 (EP)
Designated contracting statesAL,   AT,   BE,   BG,   CH,   CY,   CZ,   DE,   DK,   EE,   ES,   FI,   FR,   GB,   GR,   HR,   HU,   IE,   IS,   IT,   LI,   LT,   LU,   LV,   MC,   MK,   MT,   NL,   NO,   PL,   PT,   RO,   RS,   SE,   SI,   SK,   SM,   TR [2015/02]
Extension statesBANot yet paid
MENot yet paid
TitleGerman:Metall-Alkyliden-Komplexe mit unsymmetrischem ungesättigtem NHC-Liganden[2015/02]
English:Metal alkylidene complexes comprising an unsymmetrical unsaturated NHC ligand[2015/02]
French:Complexes d'alkylidène métalliques comprenant un ligand NHC insaturé asymétrique[2015/02]
Examination procedure05.07.2013Examination requested  [2015/02]
05.02.2014Amendment by applicant (claims and/or description)
08.07.2015Application deemed to be withdrawn, date of legal effect  [2015/53]
13.08.2015Despatch of communication that the application is deemed to be withdrawn, reason: examination fee not paid in time  [2015/53]
Fees paidPenalty fee
Additional fee for renewal fee
31.07.201503   M06   Not yet paid
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Documents cited:Search[X]WO2012056419  (BASF SE [DE]; BASF CHINA CO LTD [CN]; HASHMI A STEPHEN K [DE]; LOTHSCH) [X] 1-6,8-11 * page 41 - page 43; tables 16-20 * * page 88; example 55 * * claims 23-25 *;
 [A]  - MANUELA DELGADO-REBOLLO ET AL, "Catalytic Hydrocarbon Functionalization with Gold Complexes Containing N-Heterocyclic Carbene Ligands with Pendant Donor Groups", EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, (20120309), vol. 2012, no. 9, doi:10.1002/ejic.201101158, ISSN 1434-1948, pages 1380 - 1386, XP055086775 [A] 1-11 * page 1382; compounds 11, 12 *

DOI:   http://dx.doi.org/10.1002/ejic.201101158
 [X]  - DANOPOULOS A A ET AL, "Copper and palladium complexes with N-heterocyclic carbene ligands functionalised with carboxylate groups", JOURNAL OF ORGANOMETALLIC CHEMISTRY, ELSEVIER-SEQUOIA S.A. LAUSANNE, CH, (20080722), vol. 693, doi:10.1016/J.JORGANCHEM.2008.07.017, ISSN 0022-328X, pages 3369 - 3374, XP002529227 [X] 1-6 * page 3370; compound 6a *

DOI:   http://dx.doi.org/10.1016/j.jorganchem.2008.07.017
 [X]  - KEL VIN TAN ET AL, "Nickel(II) and Palladium(II) Complexes with Chelating N-Heterocyclic Carbene Amidate Ligands: Interplay between Normal and Abnormal Coordination Modes", ORGANOMETALLICS, (20130325), vol. 32, no. 6, doi:10.1021/om4000133, ISSN 0276-7333, pages 1913 - 1923, XP055088773 [X] 1-3,6 * page 1914; compound 2 *

DOI:   http://dx.doi.org/10.1021/om4000133
 [X]  - DEBKUMAR NANDI ET AL, "Pd(0)-Catalyzed Decarboxylative Coupling and Tandem C-H Arylation/Decarboxylation for the Synthesis of Heteroaromatic Biaryls", THE JOURNAL OF ORGANIC CHEMISTRY, (20121019), vol. 77, no. 20, doi:10.1021/jo3015837, ISSN 0022-3263, pages 9384 - 9390, XP055088784 [X] 1-4,6,8-11 * compound 1 *

DOI:   http://dx.doi.org/10.1021/jo3015837
 [X]  - WEIXI ZHANG ET AL, "Acyclic Palladium(II)-N-heterocyclic Carbene Metallacrown Ether Complexes: Synthesis, Structure and Catalytic Activity", CHINESE JOURNAL OF CHEMISTRY, (20120607), vol. 30, no. 7, doi:10.1002/cjoc.201100596, ISSN 1001-604X, pages 1423 - 1428, XP055088792 [X] 1-4,6,8-11 * compounds 5a, 5b *

DOI:   http://dx.doi.org/10.1002/cjoc.201100596
 [X]  - GONZALO VILLAVERDE ET AL, "Chiral NHC-Complexes with Dioxolane Backbone Heterogenized on MCM-41. Catalytic Activity", CHEMCATCHEM, (20110620), vol. 3, no. 8, doi:10.1002/cctc.201100119, ISSN 1867-3880, pages 1320 - 1328, XP055088794 [X] 1-4,6,8-11 * compounds 4aPd, 4bPd, 5aPd, 5bPd, 6aPd, 6bPd *

DOI:   http://dx.doi.org/10.1002/cctc.201100119
 [X]  - HUYNH H V ET AL, "Rotamers of palladium complexes bearing IR active N-heterocyclic carbene ligands: Synthesis, structural characterization and catalytic activities", JOURNAL OF ORGANOMETALLIC CHEMISTRY, ELSEVIER-SEQUOIA S.A. LAUSANNE, CH, (20081105), vol. 694, doi:10.1016/J.JORGANCHEM.2008.10.044, ISSN 0022-328X, pages 323 - 331, XP002529226 [X] 1-4,6,8-11 * compounds 3, 4, 5, 6 *

DOI:   http://dx.doi.org/10.1016/J.JORGANCHEM.2008.10.044
 [X]  - ARRAN A. D. TULLOCH ET AL, "Functionalised and chelate heterocyclic carbene complexes of palladium; synthesis and structural studies", DALTON TRANSACTIONS, (20030124), no. 4, doi:10.1039/b209231j, ISSN 1477-9226, pages 699 - 708, XP055088854 [X] 1-4,6,8-11 * compounds 10, 11, 12 *

DOI:   http://dx.doi.org/10.1039/b209231j
 [X]  - DIRK MEYER ET AL, "Palladium Complexes with Pyrimidine-Functionalized N-Heterocyclic Carbene Ligands: Synthesis, Structure and Catalytic Activity", ORGANOMETALLICS, (20090413), vol. 28, no. 7, doi:10.1021/om8009238, ISSN 0276-7333, pages 2142 - 2149, XP055054921 [X] 1-3,5,6,8-11 * compound 9c *

DOI:   http://dx.doi.org/10.1021/om8009238
 [X]  - KETZ B E ET AL, "STRUCTURE AND REACTIVITY OF AN ALLYLPALLADIUM N-HETEROCYCLIC CARBENE ENOLATE COMPLEX", ORGANOMETALLICS, ACS, WASHINGTON, DC, US, (20040101), vol. 23, no. 12, doi:10.1021/OM049838B, ISSN 0276-7333, pages 2835 - 2837, XP008049060 [X] 1-4,6 * compounds 2, 3, 4 *

DOI:   http://dx.doi.org/10.1021/om049838b
 [AD]  - REN ET AL, "A new class of o-hydroxyaryl-substituted N-heterocyclic carbene ligands and their complexes with palladium", JOURNAL OF ORGANOMETALLIC CHEMISTRY, ELSEVIER-SEQUOIA S.A. LAUSANNE, CH, (20070329), vol. 692, no. 10, doi:10.1016/J.JORGANCHEM.2007.01.028, ISSN 0022-328X, pages 2092 - 2098, XP022008542 [AD] 1 * compound 5b *

DOI:   http://dx.doi.org/10.1016/j.jorganchem.2007.01.028
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